General and Anti‐Markovnikov Selective Ni‐Catalyzed Alkylation of Arenes and Heteroarenes with Non‐Activated Olefins
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DOI: 10.1002/ejoc.202500590
Abstract: The majority of C–C coupling reactions between arenes and olefins result in the formation of branched isomer products, exhibiting what is known as Markovnikov selectivity. However, alternative catalytic strategies are required to modulate this selectivity,… read more here.
Keywords: general anti; anti markovnikov; markovnikov selective; selective catalyzed ... See more keywords
Markovnikov-Selective Hydroboration of Vinylarenes Catalyzed by a Cobalt(II) Coordination Polymer.
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DOI: 10.1021/acs.orglett.8b03431
Abstract: Highly efficient and practical hydroboration of alkenes has been catalyzed by an inexpensive and air-stable cobalt(II) coordination polymer (CP) in the presence of KO tBu. Complete conversion of alkenes to alkylboronates were performed within just… read more here.
Keywords: cobalt coordination; coordination polymer; markovnikov selective; hydroboration ... See more keywords
Markovnikov-Selective Hydroboration of Aryl Alkenes Catalyzed by Quaternary Ammonium Salts
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DOI: 10.1021/jacs.5c13555
Abstract: The development of catalytic Markovnikov-selective hydroboration of alkenes has seen significant progress; however, achieving this transformation under metal-free conditions has remained a longstanding challenge. Here, we present an organocatalytic method for the Markovnikov-selective hydroboration of… read more here.
Keywords: markovnikov selective; hydroboration aryl; quaternary ammonium; selective hydroboration ... See more keywords
Bifunctional iron-mediated multicomponent Markovnikov-selective radical hydrothiolation of alkenes
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DOI: 10.1039/d5qo00308c
Abstract: A bifunctional iron-mediated multicomponent reaction for Markovnikov-selective hydrothiolation of alkenes has been established. The reaction involves an iron-mediated hydrogen atom transfer and a single electron transfer process. read more here.
Keywords: mediated multicomponent; bifunctional iron; markovnikov selective; hydrothiolation alkenes ... See more keywords