LAUSR

Size-Matched Radical Multivalency.

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0 Published in 2017 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.6b09892

Abstract: Persistent π-radicals such as MV+• (MV refers to methyl viologen, i.e., N,N'-dimethyl-4,4'-bipyridinum) engage in weak radical-radical interactions. This phenomenon has been utilized recently in supramolecular chemistry with the discovery that MV+• and [cyclobis(paraquat-p-phenylene)]2(+•) (CBPQT2(+•)) form… read more here.

Keywords: matched radical; radical multivalency; radical pairing; complex cbpqt ... See more keywords