Utilization of Synthetic Calcium‐Phyllosilicates as Bifunctional Bases in the Matsuda‐Heck Reaction
Sign Up to like & getrecommendations! Published in 2018 at "ChemCatChem"
DOI: 10.1002/cctc.201801519
Abstract: Calcium‐phyllosilicates can successfully be used as novel bases in the Matsuda‐Heck reaction using methanol as solvent. The new experimental set‐up distinguishes itself by higher reactivity and better selectivity compared to other systems. read more here.
Keywords: bases matsuda; matsuda heck; heck reaction; calcium phyllosilicates ... See more keywords
Transition‐Metal‐Free Matsuda‐Heck Type Cross‐Coupling and Mechanistic Evidence for a Radical Mechanism
Sign Up to like & getrecommendations! Published in 2021 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202100032
Abstract: The Matsuda-Heck reaction, usually performed with palladium catalysts, can be carried out under transition metal free conditions in the presence of a KOtBu / DMF couple. This system allows, under mild temperature conditions (20 °C),… read more here.
Keywords: palladium; reaction; transition metal; matsuda heck ... See more keywords