Perspectives on Ligand Properties of N-Heterocyclic Carbenes in Iron Porphyrin Complexes.
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DOI: 10.1021/acs.inorgchem.1c02444
Abstract: There has been considerable research interest in the ligand nature of N-heterocyclic carbenes (NHCs). In this work, two six-coordinate NHC iron porphyrin complexes [FeII(TTP)(1,3-Me2Imd)2] (TTP = tetratolylporphyrin, 1,3-Me2Imd = 1,3-dimethylimidazol-2-ylidene) and [FeIII(TDCPP)(1,3-Me2Imd)2]ClO4 (TDCPP = 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrin)… read more here.
Keywords: porphyrin; perspectives ligand; me2imd; iron porphyrin ... See more keywords