A base-free terminal thorium phosphinidene metallocene and its reactivity toward selected organic molecules.
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DOI: 10.1039/c9dt00012g
Abstract: The stable base-free terminal phosphinidene thorium metallocene, [η5-1,2,4-(Me3C)3C5H2]2Th[double bond, length as m-dash]P-2,4,6-tBu3C6H2 (2), can be isolated from the reaction of the thorium dichloride complex [η5-1,2,4-(Me3C)3C5H2]2ThCl2 (1) with 2 equiv. of 2,4,6-(Me3C)3C6H2PHK in THF. The reactivity… read more here.
Keywords: thorium; complex me3c; 3c5h2 2th; phosphinidene ... See more keywords