Stable Radical Cation and Dication of a 1,4-Disilabenzene.
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DOI: 10.1021/jacs.0c12908
Abstract: The reaction of (LSi:)2 (1; L = PhC(NtBu)2) with 2 equiv of Me3SiC2C2SiMe3 resulted in the formation of (Me3SiC2)2(Me3Si)2C4Si2(L)2 (2). 2 exhibited a one-electron transfer when treated with 1 equiv of [Ph3C]+[B(C6F5)4]- to yield [(Me3SiC2)2(Me3Si)2C4Si2(L)2]ยท+[B(C6F5)4]-… read more here.
Keywords: me3si 2c4si2; radical cation; me3sic2 me3si; cation dication ... See more keywords