Expanding Bismuth Trihalide Coordination Chemistry with Trimethyltriazacyclohexane and Trimethyltriazacyclononane.
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DOI: 10.1021/acs.inorgchem.2c01483
Abstract: 1,3,5-Trimethyltriazacyclohexane, Me3tach, readily adds to bismuth triiodide to form a variety of new coordination compounds depending on the stoichiometry, solvent, and crystallization conditions. X-ray crystallographic evidence has been obtained for both 2:1 and 1:1 Me3tach:Bi… read more here.
Keywords: me3tach; coordination; chemistry; trimethyltriazacyclohexane ... See more keywords
Synthesis of Trimethyltriazacyclohexane (Me3tach) Sandwich Complexes of Uranium, Neptunium, and Plutonium Triiodides: (Me3tach)2AnI3.
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DOI: 10.1021/acs.inorgchem.2c03306
Abstract: 1,3,5-Trimethyl-1,3,5-triazacyclohexane (Me3tach) readily complexes uranium triiodide to form (Me3tach)2UI3. The complex is soluble in THF and arenes and can function as a source of UI3 to form organometallic U(III) complexes. When dissolved in pyridine (py),… read more here.
Keywords: complexes uranium; thf; me3tach; neptunium plutonium ... See more keywords