Extracting meaningful standard enthalpies and entropies of activation for surface reactions from kinetic rates
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DOI: 10.1007/s11144-020-01747-2
Abstract: While analyses based on the Arrhenius kinetic model have been successfully applied since its introduction, the Arrhenius model neglects to describe pre-exponential factor in a scientifically meaningful fashion. Since the 1930s, transition-state theory (TST), has… read more here.
Keywords: standard entropy; surface reactions; surface; activation ... See more keywords