Syntheses of Group 5 Amide Amidinates and Their Reactions with Water: Different Reactivities of Nb(V) and Ta(V) Complexes.
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DOI: 10.1021/acs.inorgchem.2c02365
Abstract: Chemistries of Nb(V) and Ta(V) compounds are essentially identical as a result of lanthanide contraction. Hydrolysis of M(NMe2)5 (M = Nb, Ta), for example, yields [M(μ3-O)(NMe2)3]4 (M = Nb, 1; Ta, 2) reported earlier. The… read more here.
Keywords: mec nipr; water; ligand; amide amidinates ... See more keywords
Syntheses and characterization of hepta-coordinated Group 4 amidinate complexes.
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DOI: 10.1039/c8dt02523a
Abstract: Tri-amidinate chloride complexes M[MeC(NiPr)2]3Cl [M = Zr (1), Hf (2)] have been prepared from MCl4 and lithium amidinate Li[MeC(NiPr)2]. The uncommon hepta-coordinated complexes Zr-Cl (1) and Hf-Cl (2) undergo metathesis reactions with 1 equiv. of… read more here.
Keywords: amidinate; syntheses characterization; hepta coordinated; characterization hepta ... See more keywords