Mechanically Interlocked Hydrogel–Elastomer Hybrids for On‐Skin Electronics
Sign Up to like & getrecommendations! Published in 2020 at "Advanced Functional Materials"
DOI: 10.1002/adfm.201909540
Abstract: Soft electronics that seamlessly interface with skin are of great interest in health monitoring and human–machine interfaces. However, achieving mechanical softness, skin adhesiveness, and high conductivity concurrently has always been a major challenge due to… read more here.
Keywords: interlocked hydrogel; elastomer hybrids; mechanically interlocked; elastomer ... See more keywords
Surface-Assembled Mechanically Interlocked Architectures.
Sign Up to like & getrecommendations! Published in 2017 at "ChemPlusChem"
DOI: 10.1002/cplu.201700065
Abstract: Since the advent of supramolecular chemistry, there has been keen interest in the synthesis of interlocked molecules, given their unique potential to act as receptors, molecular machines and even motors. Despite advances in the complexity… read more here.
Keywords: interlocked architectures; mechanically interlocked; chemistry; assembled mechanically ... See more keywords
Quasi-Barrierless Submolecular Motion in Mechanically Interlocked Carbon Nanotubes
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c03502
Abstract: The motion of molecular fragments in close contact with atomically flat surfaces is still not fully understood. Does a more favourable interaction imply a larger barrier towards motion even if ther... read more here.
Keywords: motion; mechanically interlocked; barrierless submolecular; motion mechanically ... See more keywords
Design and Synthesis of Near-Infrared Mechanically Interlocked Molecules for Specific Targeting of Mitochondria.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01922
Abstract: The entrapment of squaraine (SQ) within a molecular container to form rotaxane has been shown to improve the dye stability and the fluorescence proficiency inside the mitochondria. The macrocycle provides shelter and protects the near-infrared… read more here.
Keywords: synthesis near; design synthesis; mechanically interlocked; interlocked molecules ... See more keywords
Construction of Red Fluorescent Dual Targeting Mechanically Interlocked Molecules for Live Cancer Cell Specific Lysosomal Staining and Multicolor Cellular Imaging.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02114
Abstract: We have designed and synthesized red fluorescent mechanically interlocked molecules with dual targeting functionality for live cancer cell specific active targeting followed by selective internalization and imaging of malignant lysosomes along with real-time tracking, 3D,… read more here.
Keywords: live cancer; red fluorescent; dual targeting; cancer cell ... See more keywords
AT-CuAAC Synthesis of Mechanically Interlocked Oligonucleotides
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c01670
Abstract: We present a simple strategy for the synthesis of main chain oligonucleotide rotaxanes with precise control over the position of the macrocycle. The novel DNA-based rotaxanes were analyzed to assess the effect of the mechanical… read more here.
Keywords: cuaac synthesis; synthesis mechanically; mechanically interlocked; interlocked oligonucleotides ... See more keywords
Daisy Chain Dendrimers: Integrated Mechanically Interlocked Molecules with Stimuli-induced Dimension Modulation Feature.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c02475
Abstract: The precise construction of the high-order mechanically interlocked molecules (MIMs) with well-defined topological arrangements of multiple mechanically interlocked units has been a great challenge. Herein, we present the first successful preparation of a new family… read more here.
Keywords: chain; mechanically interlocked; interlocked molecules; chain dendrimers ... See more keywords
Mechanically Interlocked Nitrogenated Nanographenes.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c10345
Abstract: Herein, we report the synthesis of mechanically interlocked nitrogenated nanographenes. These systems have been obtained by clipping different tetralactam macrocycles around a 1.9 nm dumbbell-shaped nitrogenated nanographene. Thermal, optoelectronic, and electrochemical characterization of the different… read more here.
Keywords: nitrogenated nanographenes; interlocked nitrogenated; mechanically interlocked;
Mechanically interlocked architecture aids an ultra-stiff and ultra-hard elastically bendable cocrystal
Sign Up to like & getrecommendations! Published in 2019 at "Nature Communications"
DOI: 10.1038/s41467-019-11657-0
Abstract: Molecular crystals are not known to be as stiff as metals, composites and ceramics. Here we report an exceptional mechanical stiffness and high hardness in a known elastically bendable organic cocrystal [caffeine (CAF), 4-chloro-3-nitrobenzoic acid… read more here.
Keywords: mechanically interlocked; architecture aids; interlocked architecture; elastically bendable ... See more keywords
Dynamic covalent self-assembly of mechanically interlocked molecules solely made from peptides
Sign Up to like & getrecommendations! Published in 2021 at "Nature Chemistry"
DOI: 10.1038/s41557-021-00770-7
Abstract: Mechanically interlocked molecules (MIMs), such as rotaxanes and catenanes, have captured the attention of chemists both from a synthetic perspective and because of their role as simple prototypes of molecular machines. Although examples exist in… read more here.
Keywords: mechanically interlocked; made peptides; interlocked molecules; chemistry ... See more keywords
pH-Controlled motions in mechanically interlocked molecules
Sign Up to like & getrecommendations! Published in 2020 at "Materials Chemistry Frontiers"
DOI: 10.1039/c9qm00546c
Abstract: Mechanically interlocked molecules (MIMs), especially rotaxanes and catenanes, allow large-amplitude movement at the molecular level, making them the perfect prototypes for artificial molecular switches and machines. By applying external stimuli, the noncovalent interactions between their… read more here.
Keywords: interlocked molecules; controlled motions; motions mechanically; mechanically interlocked ... See more keywords