Hydrophobic/Hydrophilic Directionality Affects the Mechanism of Ru-Catalyzed Water Oxidation Reaction
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DOI: 10.1021/acscatal.0c02852
Abstract: From the study of supramolecular dimers of [RuVO(pda)]+ (pda = 1,10-phenanthroline-2,9-dicarboxylic acid) and [RuVO(bda)]+ (bda = 2,2′-bipyridine-6,6′-dicarboxylate) complexes, the O–O bond-forming... read more here.
Keywords: directionality affects; affects mechanism; catalyzed water; mechanism catalyzed ... See more keywords
Explicit Mechanism of Rh(I)-Catalyzed Asymmetric C-H Arylation and Facile Synthesis of Planar Chiral Ferrocenophanes.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c13542
Abstract: Mechanism-guided reaction development is a well-appreciated research paradigm in chemistry since the merging of mechanistic knowledge would accelerate the discovery of new synthetic methods. Low-valent transition metals such as Pd(0)- and Rh(I)-catalyzed C-H arylation with… read more here.
Keywords: arylation; mechanism catalyzed; asymmetric arylation; facile synthesis ... See more keywords