Articles with "mechanism iron" as a keyword



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Some features of the ammonia synthesis mechanism on an iron catalyst

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Published in 2018 at "Russian Chemical Bulletin"

DOI: 10.1007/s11172-018-2187-3

Abstract: The features of the ammonia synthesis mechanism on an iron catalyst were studied, making it possible to clarify the hydrogen role in the step of the molecular nitrogen dissociation on the catalyst surface. read more here.

Keywords: iron catalyst; mechanism iron; synthesis mechanism; ammonia synthesis ... See more keywords
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A Combined Spectroscopic and Computational Study on the Mechanism of Iron-Catalyzed Aminofunctionalization of Olefins Using Hydroxylamine Derived N–O Reagent as the “Amino” Source and “Oxidant”

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Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.1c11083

Abstract: Herein, we study the mechanism of iron-catalyzed direct synthesis of unprotected aminoethers from olefins by a hydroxyl amine derived reagent using a wide range of analytical and spectroscopic techniques (Mössbauer, Electron Paramagnetic Resonance, Ultra-Violet Visible… read more here.

Keywords: mechanism iron; iron; int; spectroscopy ... See more keywords
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Regulation of the oxidative processes as a possible mechanism of iron nanoparticles antitumor action.

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Published in 2017 at "Journal of Clinical Oncology"

DOI: 10.1200/jco.2017.35.15_suppl.e23160

Abstract: e23160Background: It has been shown that metal nanoparticles (NPs) can inhibit a tumor growth. Oxidative processes play important roles in tumor development and growth. The aim of this study was to... read more here.

Keywords: processes possible; mechanism iron; oxidative processes; iron nanoparticles ... See more keywords
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DFT Study on the Mechanism of Iron-Catalyzed Diazocarbonylation

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Published in 2020 at "Molecules"

DOI: 10.3390/molecules25245860

Abstract: The mechanism of the carbonylation of diazomethane in the presence of iron–carbonyl–phosphine catalysts has been investigated by means of DFT calculations at the M06/def-TZVP//B97D3/def2-TZVP level of theory, in combination with the SMD solvation method. The… read more here.

Keywords: mechanism iron; mechanism; study mechanism; iron catalyzed ... See more keywords