Kinetic parameters of anodic oxidation of methanol in alkali: Effect of diameter of Pd nano-catalyst, composition of electrode and solution and mechanism of the reaction
Sign Up to like & getrecommendations! Published in 2017 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2017.07.058
Abstract: Abstract Palladium nanoparticles with varying particle diameter (6.9–25.1 nm) have been synthesized by single-pot wet chemical technique in presence of poly vinyl alcohol by controlling the duration of reflux. The resulting nanoparticles have been dip-coated on… read more here.
Keywords: diameter; oxidation methanol; kinetic parameters; mechanism reaction ... See more keywords
Mechanism of the Reaction of Olefins with Nitrous Anhydride (O═N-O-N═O) to Form 1,2-Oxazetes.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c04080
Abstract: The mechanistic pathway for the formation of 1,2-oxazetes by reaction of olefins with nitrous anhydride has been clarified. The initial reaction intermediate, a β-nitroso nitrite ester that is sensitive to light, undergoes O-NO fission to… read more here.
Keywords: mechanism reaction; olefins nitrous; reaction; nitrous anhydride ... See more keywords