Mechanism of regioselectivity of rhodium-catalyzed hydrothiolation of 1,3-dienes: A computational study
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DOI: 10.1016/j.mcat.2021.111876
Abstract: Abstract Transition mental-catalyzed hydrothiolation of thiol and alkenes, alkynes or dienes is an important method to construct C-S bonds. To understand the control mechanism of the regioselectivity is of great significance in the hydrothiolation of… read more here.
Keywords: catalyzed hydrothiolation; hydrothiolation dienes; hydrothiolation; mechanism regioselectivity ... See more keywords
Mechanism and Regioselectivity of the Iron-Catalyzed Hydroboration of N-Heteroarenes: A Computational Study
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DOI: 10.1021/acs.organomet.9b00292
Abstract: Iron complex Cp*(Ph2PC6H4S)Fe was recently reported to regioselectively catalyze the hydroboration of N-heteroarenes with pinacolborane (HBpin). Density functional calculations were performed to el... read more here.
Keywords: iron catalyzed; hydroboration heteroarenes; regioselectivity iron; mechanism regioselectivity ... See more keywords