The Mechanism of Rhodium Catalyzed Allylic C-H Amination.
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DOI: 10.1021/jacs.0c01069
Abstract: Herein the mechanism of catalytic allylic C-H amination reactions promoted by Cp*Rh complexes is reported. Reaction kinetics experiments, stoichiometric studies, and DFT calculations demonstrate that the allylic C-H activation to generate a Cp*Rh(π-allyl) complex is… read more here.
Keywords: catalyzed allylic; rhodium catalyzed; mechanism rhodium; allylic amination ... See more keywords