EPR Evidence for Mechanistic Diversity of Cu(II)/Peroxygen Oxidation Systems by Tracing the Origin of DMPO Spin Adducts.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c00459
Abstract: Electron paramagnetic resonance (EPR) has been extensively used for the identification of free radicals that are generated from advanced oxidation processes (AOPs) so as to establish the reaction mechanism. However, some misinterpretations or controversies on… read more here.
Keywords: oxidation; evidence mechanistic; dmpo; epr evidence ... See more keywords
The mechanistic diversity of the selective aerobic oxidation of alcohols catalyzed by systems derived from CuI and a diamine ligand
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/d3qi00238a
Abstract: In this piece of work, CuI and its catalysis on aerobic oxidation of alcohols has been mechanistically investigated with N,N,N′,N′-tetramethylethylenediamine (TMEDA) as a ligand and 2,2,6,6-tetramethylpiperidine-N-oxyl (TEMPO) as a co-catalyst.... read more here.
Keywords: selective aerobic; aerobic oxidation; oxidation alcohols; mechanistic diversity ... See more keywords