Mechanistic exploration of the copper(i) phosphide synthesis in phosphonium-based and phosphorus-free ionic liquids.
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DOI: 10.1039/c7dt03083e
Abstract: The mechanism of the synthesis of copper(i) phosphide (Cu3-xP) in the ionic liquid (IL) trihexyl(tetradecyl)phosphonium chloride ([P66614][Cl]) was investigated. The phosphide formation is promoted by a transformation of red phosphorus (Pred) into mobile P4 molecules… read more here.
Keywords: mechanistic exploration; phosphonium; copper; copper phosphide ... See more keywords