Mechanistic kinetic modelling of enzyme-catalysed oxidation reactions of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA)
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2021.116982
Abstract: Abstract Six enzymes were tested against HMF and its oxidation intermediates to determine substrate specificity, product yield and pathways. A Michaelis–Menten kinetic mathematical model was constructed and some rate parameters calculated. The best 2,5-diformylfuran (DFF)… read more here.
Keywords: enzyme reactions; oxidation; dff; mechanistic kinetic ... See more keywords
Mechanistic kinetic modeling of simultaneous electrochemical nitrate reduction and ammonium ion oxidation in wastewater
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2021.117025
Abstract: Abstract Two kinetic models, i.e., schemes, surface adsorbed nitrogen as divergent (SND) and surface adsorbed NO as divergent (SNOD) towards NH4+ and N2 production, were developed to model simultaneous electrochemical reduction of the nitrate ion… read more here.
Keywords: kinetic modeling; oxidation; mechanistic kinetic; simultaneous electrochemical ... See more keywords
Mechanistic and kinetic study on the reaction of Pyrrole (C4H5N) with O(3P)
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DOI: 10.1016/j.chemphys.2018.06.019
Abstract: Abstract The mechanism and kinetic for the reaction of Pyrrole + O(3P) has been investigated using CCSD(T)//M06-2X method with multichannel RRKM-TST calculation. On the triplet surface, four product channels corresponding to α-C-addition, β-C-addition, N-addition and direct H-abstraction… read more here.
Keywords: pyrrole; study reaction; reaction pyrrole; kinetic study ... See more keywords