Electrophilic Aromatic Substitution Reactions: Mechanistic Landscape, Electrostatic and Electric-Field Control of Reaction Rates, and Mechanistic Crossovers.
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DOI: 10.1021/jacs.9b04982
Abstract: This study investigates the rich mechanistic landscape of the iconic electrophilic aromatic substitution (EAS) reaction class, in the gas phase, in solvents, and under stimulation by oriented external electric fields. The study uses DFT calculations,… read more here.
Keywords: reaction rates; control reaction; aromatic substitution; mechanistic landscape ... See more keywords