Mechanistic Understanding towards the Role of Cyclohexene in Enhancing the Efficiency of Manganese Porphyrin‐Catalyzed Aerobic Oxidation of Diphenylmethane
Sign Up to like & getrecommendations! Published in 2018 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201800317
Abstract: Efficiency enhanced by cyclohexene: the efficiency towards diphenylmethane oxidation, catalyzed by metalloporphyrins, is improved remarkably in the presence of cyclohexene. As a NAD(P)H‐like model, the roles of cyclohexene, promoting the initiation of a radical and… read more here.
Keywords: diphenylmethane; understanding towards; oxidation; mechanistic understanding ... See more keywords
Mechanistic Understanding of Protein Corona Formation around Nanoparticles: Old Puzzles and New Insights.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202301663
Abstract: Although a wide variety of nanoparticles (NPs) have been engineered for use as disease markers or drug delivery agents, the number of nanomedicines in clinical use has hitherto remained small. A key obstacle in nanomedicine… read more here.
Keywords: corona formation; mechanistic understanding; understanding protein; protein corona ... See more keywords
Current Mechanistic Understanding of Surface Reactions over Water-Splitting Photocatalysts
Sign Up to like & getrecommendations! Published in 2017 at "Chem"
DOI: 10.1016/j.chempr.2017.11.003
Abstract: Summary Solar water splitting for hydrogen generation over semiconductor photoelectrodes is a promising solution to the energy crisis and environmental issues. Because complex physical, chemical, and electrical processes are involved in solar energy conversion reactions,… read more here.
Keywords: water splitting; water; surface; mechanistic understanding ... See more keywords
Advancing mechanistic understanding and bioengineering of probiotic lactobacilli and bifidobacteria by genome editing.
Sign Up to like & getrecommendations! Published in 2021 at "Current opinion in biotechnology"
DOI: 10.1016/j.copbio.2020.12.015
Abstract: Typical traditional probiotics lactobacilli and bifidobacteria are gaining great interest to be developed as living diagnostics and therapeutics for improving human health. However, the mechanistic basis underlying their inherent health beneficial property remain incompletely understood… read more here.
Keywords: genome editing; advancing mechanistic; mechanistic understanding; lactobacilli bifidobacteria ... See more keywords
Integrating Electrochemical and Statistical Analysis Tools for Molecular Design and Mechanistic Understanding.
Sign Up to like & getrecommendations! Published in 2020 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.9b00527
Abstract: Medicinal chemistry campaigns set the foundation for streamlined molecular design strategies through the development of quantitative structure-activity models. Our group's enduring underlying interest in reaction mechanism propelled our adaption of a similar strategy to unite… read more here.
Keywords: molecular design; insight; analysis; mechanistic understanding ... See more keywords
Silver Nanocubes: From Serendipity to Mechanistic Understanding, Rational Synthesis, and Niche Applications
Sign Up to like & getrecommendations! Published in 2023 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.3c00472
Abstract: Silver has long been interwoven into human history, and its uses have evolved from currency and jewelry to medicine, information technology, catalysis, and electronics. Within the last century, the development of nanomaterials has further solidified… read more here.
Keywords: serendipity mechanistic; silver nanocubes; synthesis; understanding rational ... See more keywords
Mechanistic Understanding of Lanthipeptide Biosynthetic Enzymes
Sign Up to like & getrecommendations! Published in 2017 at "Chemical Reviews"
DOI: 10.1021/acs.chemrev.6b00591
Abstract: Lanthipeptides are ribosomally synthesized and post-translationally modified peptides (RiPPs) that display a wide variety of biological activities, from antimicrobial to antiallodynic. Lanthipeptides that display antimicrobial activity are called lantibiotics. The post-translational modification reactions of lanthipeptides… read more here.
Keywords: understanding lanthipeptide; lanthipeptide biosynthetic; post translational; mechanistic understanding ... See more keywords
Organocatalytic Cyclopropanation of (E)-Dec-2-enal: Synthesis, Spectral Analysis and Mechanistic Understanding
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Chemical Education"
DOI: 10.1021/acs.jchemed.7b00566
Abstract: An undergraduate experiment combining synthesis, NMR analysis and mechanistic understanding is reported. The students perform an organocatalyzed cyclopropanation reaction of (E)-dec-2-enal and are then required to determine the diastereoselectivity and assign the relative configuration of… read more here.
Keywords: cyclopropanation; dec enal; analysis mechanistic; mechanistic understanding ... See more keywords
Mechanistic Understanding of NO2 Dissociation on a Rutile TiO2 (110) Surface: An Electronic Structure Study
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c00525
Abstract: Understanding the mechanism of NO2 interaction on semiconductor surfaces such as TiO2 is a key step in designing the catalytic processes for conversion of NO2 to useful products. In the present wor... read more here.
Keywords: understanding no2; tio2 110; mechanistic understanding; dissociation rutile ... See more keywords
Toward the Mechanistic Understanding of Enzymatic CO 2 Reduction
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c00086.s001
Abstract: Reducing CO2 is a challenging chemical transformation that biology solves easily, with high efficiency and specificity. In particular, formate dehydrogenases are of great interest since they reduce CO2 to formate, a valuable chemical fuel and… read more here.
Keywords: reduction; co2 reduction; mechanistic understanding; toward mechanistic ... See more keywords
Toward a mechanistic understanding of electrocatalytic nanocarbon
Sign Up to like & getrecommendations! Published in 2021 at "Nature Communications"
DOI: 10.1038/s41467-021-23486-1
Abstract: Electrocatalytic nanocarbon (EN) is a class of material receiving intense interest as a potential replacement for expensive, metal-based electrocatalysts for energy conversion and chemical production applications. The further development of EN will require an intricate… read more here.
Keywords: understanding electrocatalytic; toward mechanistic; mechanistic understanding; electrocatalytic nanocarbon ... See more keywords