Mechanochemical conversion of nano potassium hydrogen terephthalate to thallium analogue nanoblocks with strong hydrogen bonding and straight chain metalophillic interactions
Sign Up to like & getrecommendations! Published in 2018 at "Applied Organometallic Chemistry"
DOI: 10.1002/aoc.4313
Abstract: Irreversible mechanochemical conversion of three-dimensional KI coordination polymer [K(μ6-HTA)]n (1), [H2TA = terephetalic acid], prepared by sonochemical procedure, to TlI analogue coordination polymer nanoblocks was studied. The structure of [Tl(μ3-HTA)]n (2) is exactly the same… read more here.
Keywords: mechanochemical conversion; hydrogen; chemistry; strong hydrogen ... See more keywords
Mechanochemical Conversion of Aromatic Amines to Aryl Trifluoromethyl Ethers
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02611
Abstract: Increased interest in the trifluoromethoxy group in organic synthesis and medicinal chemistry has induced a demand for new, selective, general, and faster methods applicable to natural products and highly functionalized compounds at a later stage… read more here.
Keywords: mechanochemical conversion; aromatic amines; trifluoromethyl ethers; aryl trifluoromethyl ... See more keywords