Achieving Regioselective Control for Mechanochemical Reactions: A Planetary Ball‐Milling, Ru‐Catalyzed Synthesis of 3,4‐ and 3,4,5‐Isoxazoles
Sign Up to like & getrecommendations! Published in 2024 at "ChemCatChem"
DOI: 10.1002/cctc.202400406
Abstract: A mechanochemical‐enabled Ru‐catalyzed regioselective synthesis of 3,4‐isoxazoles and 3,4,5‐isoxazoles from terminal and internal alkynes and hydroxyimidoyl chlorides is reported. This solid‐state and solvent‐free approach carefully examines the impact of the milling conditions on regiocontrol in… read more here.
Keywords: synthesis isoxazoles; synthesis; mechanochemical reactions; regioselective control ... See more keywords
Multimechanophore Graft Polymers: Mechanochemical Reactions at Backbone–Arm Junctions
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b01996
Abstract: Typical multimechanophore polymers (MMPs) are comprised of numerous mechanophores (force-responsive moieties) distributed throughout the backbone of linear polymers. We have developed a new MMP des... read more here.
Keywords: mechanochemical reactions; backbone arm; polymers mechanochemical; multimechanophore graft ... See more keywords
Extending the Hammett correlation to mechanochemical reactions.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06487a
Abstract: Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge… read more here.
Keywords: mechanochemical reactions; extending hammett; chemistry; correlation mechanochemical ... See more keywords
Mechanochemical Reactions within Graft Copolymeric Assemblies： Ultrasound-Induced Multimechanophore Activation, Arm Chain Scission, and Aggregation Morphology/Size Changes
Sign Up to like & getrecommendations! Published in 2023 at "Polymer Chemistry"
DOI: 10.1039/d2py01515c
Abstract: The development of nanosized aggregates that respond to mechanical stimuli is of great importance for applications related to ultrasound imaging or sensors, etc. In this work, we fabricate model assemblies... read more here.
Keywords: graft copolymeric; mechanochemical reactions; within graft; copolymeric assemblies ... See more keywords
Shaking Things from the Ground-Up: A Systematic Overview of the Mechanochemistry of Hard and High-Melting Inorganic Materials
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28020897
Abstract: We provide a systematic overview of the mechanochemical reactions of inorganic solids, notably simple binary compounds, such as oxides, nitrides, carbides, sulphides, phosphides, hydrides, borides, borane derivatives, and related systems. Whereas the solid state has… read more here.
Keywords: mechanochemistry hard; mechanochemical reactions; high melting; hard high ... See more keywords