Iodine-Mediated Alkoxyselenylation of Alkenes and Dienes with Elemental Selenium
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DOI: 10.3390/molecules27196169
Abstract: A one-pot synthesis of linear and cyclic β-alkoxyselenides is developed through the iodine-mediated three-component reaction of elemental selenium with alkenes (dienes) and alcohols. Selenylation of 1,5-hexadiene gives 2,5-di(methoxymethyl)tetrahydroselenophene and 2-methoxy-6-(methoxymethyl)tetrahydro-2H-selenopyran via the 5-exo-trig and 6-endo-trig… read more here.
Keywords: alkenes dienes; alkoxyselenylation alkenes; mediated alkoxyselenylation; iodine mediated ... See more keywords