Strong Ferromagnetic Exchange Coupling Mediated by a Bridging Tetrazine Radical in a Dinuclear Nickel Complex.
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DOI: 10.1021/acs.inorgchem.7b01812
Abstract: The radical bridged compound [(Ni(TPMA))2-μ-bmtz•-](BF4)3·3CH3CN (bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine, TPMA = tris(2-pyridylmethyl)amine) exhibits strong ferromagnetic exchange between the S = 1 NiII centers and the bridging S = 1/2 bmtz radical with J = 96 ±… read more here.
Keywords: mediated bridging; ferromagnetic exchange; strong ferromagnetic; coupling mediated ... See more keywords