Molybdenum-Mediated Coupling of Carbon Monoxide to a C3 Product on a Single Metal Site.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00266
Abstract: The synthesis and characterization of a series of naphthalenediyl-diphosphine molybdenum complexes are reported. A novel dicarbonyl-Mo complex (3) converts to a bis(siloxy)acetylene complex (5) upon reduction and treatment with a silyl electrophile, Me3SiCl. This process… read more here.
Keywords: coupling carbon; molybdenum; monoxide product; mediated coupling ... See more keywords
Base-Mediated Coupling Reactions of Benzenesulfonyl Azides with Proline: Synthesis of Proline-Derived Benzenesulfonamides
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DOI: 10.1021/acsomega.1c05331
Abstract: Sulfonamides and lipids are widely found in natural products, bioactive substances, and pharmaceuticals. Here, we report N-sulfonylation and esterification of carboxylic acids in an environment-friendly one-pot tandem protocol involving 1,2-dichloroethane (DCE). Moreover, 1,8-diazabicyclo (5.4.0) undec-7-ene… read more here.
Keywords: mediated coupling; coupling reactions; reactions benzenesulfonyl; base ... See more keywords
Versatility of Boron-Mediated Coupling Reaction of Oxetanes and Epoxides with CO2: Selective Synthesis of Cyclic Carbonates or Linear Polycarbonates
Sign Up to like & getrecommendations! Published in 2020 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.0c04768
Abstract: Achieving simultaneously high selectivity and high rate in the coupling reaction of CO2 with poorly reacting oxetanes remains a major challenge. Here, the selective and nearly quantitative conversi... read more here.
Keywords: boron mediated; versatility boron; coupling reaction; mediated coupling ... See more keywords