Zinc-Mediated Efficient and Selective Reduction of Carbonyl Compounds
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DOI: 10.1002/ejoc.201700887
Abstract: We herein describe for the first time that an optimized combination of Zn and NH4Cl can be used for the selective reduction of aldehydes and ketones to the corresponding alcohols. The aldehyde and keto groups… read more here.
Keywords: reduction; selective reduction; reduction carbonyl; mediated efficient ... See more keywords
DMSO/tBuONa/O2-mediated efficient syntheses of diverse quinoxalines through α-imino radicals.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00086a
Abstract: Herein, we describe an efficient method involving the synthesis of diverse quinoxalines using the DMSO/tBuONa/O2 system as a single-electron oxidant to form α-imino radicals and nitrogen radicals for the direct construction of C-N bonds. This… read more here.
Keywords: imino radicals; dmso tbuona; mediated efficient; tbuona mediated ... See more keywords