Electrochemical PINOylation of Methylarenes: Improving the Scope and Utility of Benzylic Oxidation through Mediated Electrolysis.
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DOI: 10.1021/jacs.2c05974
Abstract: A mediated electrosynthetic method has been developed for selective benzylic oxidation of methylarenes. Phthalimide-N-oxyl (PINO) radical generated by proton-coupled electrochemical oxidation of N-hydroxypthalimide serves as a hydrogen atom-transfer (HAT) mediator and as a radical trap… read more here.
Keywords: oxidation; benzylic oxidation; mediated electrolysis; scope ... See more keywords
Iodine Redox-Mediated Electrolysis for Energy-Efficient Chlorine Regeneration from Gaseous HCl
Sign Up to like & getrecommendations! Published in 2017 at "Journal of The Electrochemical Society"
DOI: 10.1149/2.0461707jes
Abstract: Hydrogen chloride (HCl) by-product is often produced from chlorine-consuming processes. Traditional electrochemical processes for converting HCl to chlorine (Cl2) are completed by anodic oxidation reaction coupled with cathodic reduction reactions (two major types: hydrogen evolution… read more here.
Keywords: iodine redox; redox mediated; redox; electrolysis energy ... See more keywords