Metalate‐Mediated Functionalization of P4 by Trapping Anionic [Cp*Fe(CO)2(η1‐P4)]− with Lewis Acids
Sign Up to like & getrecommendations! Published in 2017 at "ChemistryOpen"
DOI: 10.1002/open.201700027
Abstract: Abstract The development of selective functionalization strategies of white phosphorus (P4) is important to avoid the current chlorinated intermediates. The use of transition metals (TMs) could lead to catalytic procedures, but these are severely hampered… read more here.
Keywords: metalate mediated; mediated functionalization; lewis acids; functionalization trapping ... See more keywords
Stem cell-mediated functionalization of titanium implants
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Materials Science: Materials in Medicine"
DOI: 10.1007/s10856-017-5944-1
Abstract: Prosthetic implants are used daily to treat edentulous people and to restore mobility in patients affected by skeletal defects. Titanium (Ti) is the material of choice in prosthetics, because it can form a stable bond… read more here.
Keywords: stem cell; cell; cell mediated; mediated functionalization ... See more keywords
Palladium-Mediated Functionalization of Benzofuran and Benzothiophene Cores
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00682
Abstract: The palladation reactions of 2-heteroaromatic primary phenethylamines bearing a benzofuran and benzothiophene nuclei have been studied. We have assessed the reactivity of the corresponding dimeric six-membered palladacycles (arising from C–H metalation) toward neutral ligands and… read more here.
Keywords: benzofuran benzothiophene; mediated functionalization; functionalization benzofuran; palladium mediated ... See more keywords
Direct alkylheteroarylation of alkenes via photoredox mediated C-H functionalization.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06484e
Abstract: The direct alkylheteroarylation of alkenes with cyclic and acyclic ethers via distal heteroaryl ipso-migration has been accomplished through the design of a photoredox-mediated C-H functionalization pathway. The use of inexpensive ethers as radical precursors combined… read more here.
Keywords: photoredox mediated; alkylheteroarylation alkenes; direct alkylheteroarylation; mediated functionalization ... See more keywords
Cesium carbonate mediated C-H functionalization of perhalogenated 12-vertex carborane anions.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00173j
Abstract: C-H functionalization of undecahalogenated carborane anions, [HCB11X11-] (X = Cl, Br, I), is performed with Cs2CO3 in acetonitrile. We show that the requisite Cl, Br and I carborane dianions can all be efficiently accessed with… read more here.
Keywords: mediated functionalization; carbonate mediated; functionalization; carborane anions ... See more keywords
In vitro evaluation of NaOCl-mediated functionalization of biologically aged titanium surfaces.
Sign Up to like & getrecommendations! Published in 2020 at "Dental materials journal"
DOI: 10.4012/dmj.2019-358
Abstract: The aim of this study was to evaluate the NaOCl-mediated biofunctionalization of titanium surfaces. Titanium disks stored for 2 weeks were immersed in 5% NaOCl solution for 24 h. A disk immersed in distilled water… read more here.
Keywords: evaluation naocl; mediated functionalization; vitro evaluation; naocl mediated ... See more keywords