Articles with "mediated hydrogen" as a keyword



Photo from wikipedia

Ionic conductivity mediated by hydrogen bonding in liquid crystalline 4-n-alkoxybenzoic acids

Sign Up to like & get
recommendations!
Published in 2019 at "Journal of Molecular Structure"

DOI: 10.1016/j.molstruc.2019.07.072

Abstract: The authors would like to acknowledge Mathew Abdy and Daniel Zaton for their help preparing the samples, Prof. Corrie Imrie and Prof. John Storey for their continuous advice, and the School of Engineering (University of… read more here.

Keywords: mediated hydrogen; liquid crystalline; ionic conductivity; bonding liquid ... See more keywords
Photo by norbertkowalczyk from unsplash

Photoinduced Remote C(sp3)-H Imination Enabled by Vinyl Radical-Mediated 1,5-Hydrogen Atom Transfer.

Sign Up to like & get
recommendations!
Published in 2023 at "Organic letters"

DOI: 10.1021/acs.orglett.3c00510

Abstract: A vinyl radical-mediated 1,5-hydrogen atom transfer strategy for remote C(sp3)-H imination under visible-light-induced photochemical metal-free conditions afforded diverse γ-imino alkenes with excellent stereoselectivity. Oxime ester-based bifunctional reagents provided not only nucleophilic alkyl radicals for radical… read more here.

Keywords: hydrogen atom; hydrogen; mediated hydrogen; atom transfer ... See more keywords
Photo from wikipedia

Stereoselective Synthesis of C,C-Glycosides from exo-Glycals Enabled by Iron-Mediated Hydrogen Atom Transfer.

Sign Up to like & get
recommendations!
Published in 2019 at "Organic letters"

DOI: 10.1021/acs.orglett.9b02496

Abstract: We describe herein a convenient strategy for the construction of C,C-glycoside building blocks via the intermediacy of tertiary pseudoanomeric radicals. Application of an iron-mediated hydrogen atom transfer/Michael-Giese coupling enables the anomeric quaternization of readily available… read more here.

Keywords: iron mediated; atom transfer; hydrogen atom; exo glycals ... See more keywords