Synthesis of β-Silyl α-Amino Acids via Visible-Light-Mediated Hydrosilylation.
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DOI: 10.1021/acs.orglett.1c00065
Abstract: An expedient synthesis of β-silyl α-amino acids is reported via the application of visible-light-mediated hydrosilylation. The reaction utilizes readily accessible and structurally diverse hydrosilanes to provide radicals for conjugate addition to dehydroalanine ester and analogues.… read more here.
Keywords: amino acids; silyl amino; mediated hydrosilylation; light mediated ... See more keywords