Nonaqueous Li-Mediated Nitrogen Reduction: Taking Control of Potentials
Sign Up to like & getrecommendations! Published in 2023 at "ACS Energy Letters"
DOI: 10.1021/acsenergylett.2c02697
Abstract: The performance of the Li-mediated ammonia synthesis has progressed dramatically since its recent reintroduction. However, fundamental understanding of this reaction is slower paced, due to the many uncontrolled variables influencing it. To address this, we… read more here.
Keywords: nonaqueous mediated; taking control; nitrogen reduction; reduction taking ... See more keywords
Fe-Mediated Nitrogen Fixation with a Metallocene Mediator: Exploring p Ka Effects and Demonstrating Electrocatalysis.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b02335
Abstract: Substrate selectivity in reductive multielectron/proton catalysis with small molecules such as N2, CO2, and O2 is a major challenge for catalyst design, especially where the competing hydrogen evolution reaction (HER) is thermodynamically and kinetically competent.… read more here.
Keywords: nitrogen fixation; fixation metallocene; metallocene mediator; mediated nitrogen ... See more keywords
The origin of overpotential in lithium-mediated nitrogen reduction.
Sign Up to like & getrecommendations! Published in 2023 at "Faraday discussions"
DOI: 10.1039/d2fd00156j
Abstract: The verification of the lithium-mediated nitrogen reduction system in 2019 has led to an explosion in the literature focussing on improving the metrics of faradaic efficiency, stability, and activity. However, while the literature acknowledges the… read more here.
Keywords: origin overpotential; nitrogen reduction; lithium; lithium mediated ... See more keywords