Visible-Light-Mediated α-Oxygenation of 3-(N ,N -Dimethylaminomethyl)-Indoles to Aldehydes
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DOI: 10.1002/ejoc.201801335
Abstract: Results: We have developed a visible-light-mediated oxygenation of indole tertiary amines into corresponding aldehydes, using photoredox system (Scheme 1). Based on Stern-Volmer plots, series of quenching experiments mechanism is proposed. Mentioned method allows to obtain… read more here.
Keywords: oxygenation dimethylaminomethyl; light mediated; visible light; mediated oxygenation ... See more keywords
Chlorine-radical-mediated C-H oxygenation reaction under light irradiation.
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DOI: 10.1039/d3cc01057k
Abstract: The oxygenation of C(sp3)-H bonds is a key chemical reaction in the production of fine chemicals and pharmaceuticals. Hydrogen atom transfer has recently gained significant attention for its ability to functionalise C-H bonds. The C-H… read more here.
Keywords: chlorine radical; mediated oxygenation; oxygenation; light irradiation ... See more keywords
Peroxide-Mediated Oxygenation of Organic Compounds by Fungal Peroxygenases
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DOI: 10.3390/antiox11010163
Abstract: Unspecific peroxygenases (UPOs), whose sequences can be found in the genomes of thousands of filamentous fungi, many yeasts and certain fungus-like protists, are fascinating biocatalysts that transfer peroxide-borne oxygen (from H2O2 or R-OOH) with high… read more here.
Keywords: compounds fungal; organic compounds; mediated oxygenation; oxygenation ... See more keywords