LiCl-Mediated and Palladium-Catalyzed Oxidative Cyclization of Furan-Ynes via Dearomatizing Alkoxyalkenylation of Furan.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01157
Abstract: A LiCl-mediated and palladium(II)-catalyzed oxidative cyclization of furan-ynes via dearomatizing alkoxyalkenylation of furan is reported to afford polyfunctionalized spiro-dihydrofurans with diastereospecification and high Z/E selectivity. This protocol is likely to involve chloropalladation of alkynes, subsequent… read more here.
Keywords: licl mediated; furan; mediated palladium; catalyzed oxidative ... See more keywords
DMSO-mediated palladium-catalyzed cyclization of two isothiocyanates via C–H sulfurization: a new route to 2-aminobenzothiazoles
Sign Up to like & getrecommendations! Published in 2019 at "RSC Advances"
DOI: 10.1039/c8ra09784d
Abstract: DMSO-initiated coupling of two isothiocyanates; Pd-catalyzed C–H sulfurization. read more here.
Keywords: mediated palladium; catalyzed cyclization; dmso mediated; palladium catalyzed ... See more keywords
A borane-mediated palladium-catalyzed reductive allylic alkylation of α,β-unsaturated carbonyl compounds†
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/c9sc05970a
Abstract: The development of the palladium-catalyzed allylic alkylation of in situ generated boron enolates via tandem 1,4-hydroboration is reported. Investigation of the reaction revealed insights into specific catalyst electronic features as well as a profound leaving… read more here.
Keywords: allylic alkylation; palladium catalyzed; mediated palladium; alkylation ... See more keywords