Hydrolyzable Poly[Poly(Ethylene Glycol) Methyl Ether Acrylate]-Colistin Prodrugs through Copper-Mediated Photoinduced Living Radical Polymerization.
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DOI: 10.1021/acs.bioconjchem.7b00242
Abstract: Through the recently developed copper-mediated photoinduced living radical polymerization (CP-LRP), a novel and well-defined polymeric prodrug of the antimicrobial lipopeptide colistin has been developed. A colistin initiator (Boc5-col-Br2) was synthesized through the modification of colistin… read more here.
Keywords: polymerization; copper mediated; colistin; photoinduced living ... See more keywords
Aryl Ketone Mediated Photoinduced Radical Coupling for the Alkylation of Benzazoles Employing Saturated Heterocyclic Compounds
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DOI: 10.1055/s-0037-1611895
Abstract: An aryl ketone mediated synthesis of 2-alkylated benzazoles was achieved via radical coupling under photoirradiation starting from saturated heterocycles and 2-sulfonylated benzazoles, such as benzothiazoles, benzoxazole, and benzimidazole. Heterocyclic compounds, including a cyclic ether, azacycles,… read more here.
Keywords: aryl ketone; mediated photoinduced; heterocyclic compounds; radical coupling ... See more keywords