Grafting from Starch Nanoparticles with Synthetic Polymers via Nitroxide-Mediated Polymerization.
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201800834
Abstract: Nitroxide-mediated polymerization (NMP) is employed to graft synthetic polymers from polysaccharides. This work demonstrates the first successful polymer grafting from starch nanoparticles (SNPs) via NMP. To graft synthetic polymers from the SNPs' surface, the SNPs… read more here.
Keywords: grafting starch; starch nanoparticles; mediated polymerization; nitroxide mediated ... See more keywords
Photolabile Well-Defined Polystyrene Grafted on Silica Nanoparticle via Nitroxide-Mediated Polymerization (NMP).
Sign Up to like & getrecommendations! Published in 2021 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202100181
Abstract: Herein, the synthesis of a novel nitroxide-mediated polymerization (NMP) initiator bearing a photolabile ortho-nitrobenzyl (oNB) group allowing surface-initiated NMP preparation of well-defined photoresponsive polystyrene grafted on silica nanoparticles is described. The photocleavable and photoresponsive properties… read more here.
Keywords: well defined; grafted silica; mediated polymerization; nitroxide mediated ... See more keywords
Nitroxide-mediated polymerization of methacrylates in the presence of 4-vinyl pyridine as controlling comonomer
Sign Up to like & getrecommendations! Published in 2019 at "Polymer"
DOI: 10.1016/j.polymer.2019.04.003
Abstract: Abstract The controlled polymerization of methacrylic monomers by nitroxide-mediated polymerization (NMP) still represents a challenge in polymer science. This issue can be circumvented by the addition of a small amount of a comonomer known to… read more here.
Keywords: controlling comonomer; mediated polymerization; vinyl pyridine; nitroxide mediated ... See more keywords
Design and synthesis of trivalent Tn glycoconjugate polymers by nitroxide-mediated polymerization
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.130776
Abstract: Abstract A new synthetic method for preparing Tn glycoconjugate polymers, containing tumor-associated carbohydrate antigens, by controlled living radical polymerization is reported. To mimic the authentic structures of Tn glycopeptide antigens and to explore the controlled… read more here.
Keywords: polymerization; controlled living; glycoconjugate polymers; mediated polymerization ... See more keywords
“Living” Polymer Dispersity Quantification for Nitroxide-Mediated Polymerization Systems by Mimicking a Monodispersed Polymer Blending Strategy
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.0c02029
Abstract: The quantification of dispersity is an indispensable part of characterizing polymers. In this work, general dispersity equations for “living” polymers obtained by nitroxide-mediated polymerization ... read more here.
Keywords: dispersity; polymer; mediated polymerization; nitroxide mediated ... See more keywords
Tunable Hierarchically Structured Meso-Macroporous Carbon Spheres from a Solvent-Mediated Polymerization-Induced Self-Assembly.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12977
Abstract: Herein, we report a versatile solvent-mediated polymerization-induced self-assembly (PISA) strategy to directly synthesize highly N-doped hierarchically porous structured carbon spheres with a tunable meso-macroporous configuration. The introduction of intermolecular hydrogen bonds is verified to enhance… read more here.
Keywords: carbon spheres; polymerization induced; mediated polymerization; solvent mediated ... See more keywords
Facile synthesis of cylindrical molecular brushes via Lewis pair-mediated polymerization
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DOI: 10.1039/c8py01257a
Abstract: We demonstrate the first application of Lewis pair-mediated polymerization (LPP) in the efficient synthesis of cylindrical molecular brushes bearing poly(methyl methacrylate) and polylactone side chains. Poly(N-heterocyclic olefin) (poly(NHO)) as a macroinitiator precursor was firstly prepared… read more here.
Keywords: molecular brushes; polymerization; lewis pair; pair mediated ... See more keywords
Ethylene Glycol Dicyclopentenyl (Meth)Acrylate Homo and Block Copolymers via Nitroxide Mediated Polymerization
Sign Up to like & getrecommendations! Published in 2019 at "Materials"
DOI: 10.3390/ma12091547
Abstract: Nitroxide-mediated polymerization (NMP), (homo and block copolymerization with styrene (S) and butyl methacrylate/S) of ethylene glycol dicyclopentenyl ether (meth)acrylates (EGDEA and EGDEMA) was studied using BlocBuilder alkoxyamines. EGDEA homopolymerization was not well-controlled, independent of temperature… read more here.
Keywords: homo block; block; mediated polymerization; nitroxide mediated ... See more keywords