Mechanism of Ir-Mediated Selective Pyridine o-C–H Activation: The Role of Lewis Acidic Boryl Group
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.1c00310
Abstract: General mechanistic scenarios including boryl-directed (BD) oxidative addition, nondirected (nonBD) oxidative addition, and boryl–metal cooperation via B-hydrido type (BHMC) or B-carbanion type (BC... read more here.
Keywords: selective pyridine; boryl; activation role; mediated selective ... See more keywords
Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH3-Mediated Selective Catalytic Reduction
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c06270
Abstract: The NH3-mediated selective catalytic reduction (NH3-SCR) of NOx over Cu-ion-exchanged chabazite (Cu-CHA) catalysts is the basis of the technology for abatement of NOx from diesel vehicles. A crucial step in this reaction is the activation… read more here.
Keywords: reduction; mediated selective; reaction; structure ... See more keywords
PINO/NHPI-mediated selective oxidation of cycloalkenes to cycloalkenones via a photo-electrochemical method.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03540k
Abstract: The selective photo-electrochemical oxidation of cyclohexene to 2-cyclohexene-1-one was successfully performed with excellent Faraday efficiency (>99%) via indirect oxidation with a PINO/NHPI mediator and O2 on a BiVO4/WO3 photoanode under low applied bias. read more here.
Keywords: oxidation; photo electrochemical; mediated selective; nhpi mediated ... See more keywords
Bromide-mediated, C2-selective, and oxygenative alkylation of pyridinium salts using alkenes and molecular oxygen.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc06138d
Abstract: Herein, we report a bromide-mediated, C2-selective, and oxygenative alkylation of pyridinium salts using alkenes and O2 for the synthesis of important β-2-pyridyl ketones. Notably, a quaternary carbon center was successfully installed at the C2-position of… read more here.
Keywords: oxygenative alkylation; alkylation pyridinium; mediated selective; bromide mediated ... See more keywords
Garcinia cambogia attenuates adipogenesis by affecting CEBPB and SQSTM1/p62-mediated selective autophagic degradation of KLF3 through RPS6KA1 and STAT3 suppression.
Sign Up to like & getrecommendations! Published in 2021 at "Autophagy"
DOI: 10.1080/15548627.2021.1936356
Abstract: The overexpansion of adipose tissues leads to obesity and eventually results in metabolic disorders. Garcinia cambogia (G. cambogia) has been used as an antiobesity supplement. However, the molecular mechanisms underlying the effects of G. cambogia… read more here.
Keywords: cambogia; sqstm1 p62; cebpb; mediated selective ... See more keywords
OPTN (optineurin)-mediated selective autophagy prevents neurodegeneration due to herpesvirus infection
Sign Up to like & getrecommendations! Published in 2022 at "Autophagy"
DOI: 10.1080/15548627.2022.2037223
Abstract: ABSTRACT Very little is known about the mechanisms that restrict neurotropic herpesviruses such as herpes simplex virus-1 (HSV-1) from infecting the central nervous system (CNS) and causing widespread death of neurons. Likewise, HSV-1 is thought… read more here.
Keywords: mediated selective; optineurin mediated; infection; neurodegeneration ... See more keywords
Palmitoylation facilitates inflammation through suppressing NOD2 degradation mediated by the selective autophagy receptor SQSTM1
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DOI: 10.1080/15548627.2022.2054041
Abstract: ABSTRACT The intracellular pattern recognition receptor NOD2 senses bacterial peptidoglycan to drive proinflammatory and antimicrobial responses. Dysregulation of NOD2 signaling confers susceptibility to several immunological and inflammatory diseases. Although palmitoylation of NOD2 is required for… read more here.
Keywords: inflammation; mediated selective; degradation; receptor ... See more keywords
Complement-Mediated Selective Tumor Cell Lysis Enabled by Bi-Functional RNA Aptamers
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DOI: 10.3390/genes13010086
Abstract: Unlike microbes that infect the human body, cancer cells are descended from normal cells and are not easily recognizable as “foreign” by the immune system of the host. However, if the malignant cells can be… read more here.
Keywords: cancer; cancer cells; complement mediated; lysis ... See more keywords