Copper‐Mediated C(sp2)‐S Coupling: a Strategy for the Preparation of S‐Aryl Dithiocarbamates
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202500419
Abstract: We developed an efficient copper‐mediated one‐pot, three‐component reaction for synthesizing S‐aryl dithiocarbamates from aliphatic amines, phenylboronic acid, and carbon disulfide. This approach proceeds under mild, ambient conditions without requiring a base or additional additives, significantly… read more here.
Keywords: chemistry; copper mediated; aryl dithiocarbamates; mediated sp2 ... See more keywords
Cu(OTf)2-mediated C(sp2)–H arylsulfonylation of enamides via the insertion of sulfur dioxide
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c8qo01144c
Abstract: A stereoselective Cu(OTf)2-mediated C(sp2)–H sulfonylation of enamides with arylsulfonyl radicals generated in situ from DABSO and diazonium salts is developed. read more here.
Keywords: mediated sp2; via insertion; enamides via; otf mediated ... See more keywords