KIO3-Mediated γ-C(sp3)-H Sulfenylation of Enaminones.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02824
Abstract: A metal-free regioselective γ-C(sp3)-H sulfenylation of enaminones with heterocyclic thiols is reported. This transformation is efficient, mild, scalable, and environmentally friendly and tolerates a large variety of enaminones substrates and heterocyclic thiols. The utility of… read more here.
Keywords: mediated sp3; kio3 mediated; sulfenylation enaminones; sp3 sulfenylation ... See more keywords
Gold mediated sp3αC-H functionalization of steroidal diglycoside and their anti-cancer evaluation
Sign Up to like & getrecommendations! Published in 2019 at "Natural Product Research"
DOI: 10.1080/14786419.2019.1696789
Abstract: Abstract C(sp3)-H alkylation at α-position of methyl-keto group on D-ring of Steroidal diglycoside (SG) with (i) C=N of Schiff base imines to form amine derivatives and (ii) C=C of acrylate Michael acceptors to form Markovnikov… read more here.
Keywords: steroidal diglycoside; sp3 functionalization; mediated sp3; cancer ... See more keywords