Organo‐, Metal‐, and Enzyme‐Mediated Stereoselective Transformations of α‐Angelica Lactone
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DOI: 10.1002/cctc.202500060
Abstract: α‐Angelica lactone is a five‐membered heterocycle belonging to the rich family of butenolides, a key motif, present in a great variety of bioactive and natural products. Moreover, it is a small compound attainable from the… read more here.
Keywords: organo metal; mediated stereoselective; metal enzyme; enzyme mediated ... See more keywords
Brønsted Base Mediated Stereoselective Diphosphination of Terminal Alkynes with Diphosphanes.
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DOI: 10.1021/acs.orglett.7b01209
Abstract: A Brønsted base mediated stereoselective diphosphination of terminal alkynes with diphosphanes proceeds to deliver the corresponding (E)-1,2-diphosphinoethenes in good yields. The reaction of aromatic alkynes occurs efficiently in the presence of a catalytic amount of… read more here.
Keywords: base mediated; mediated stereoselective; diphosphination terminal; nsted base ... See more keywords
N-Acylazole mediated stereoselective and regioselective synthesis ofN-substituted azole acrylonitriles
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DOI: 10.3906/kim-1903-56
Abstract: Regioand stereoselective synthesis of N -substituted azole acrylonitriles has been achieved smoothly in N,N -dimethylformamide (DMF) in the presence of potassium carbonate (K2 CO3) as a base catalyst. N -Substituted azole acrylonitriles were obtained in… read more here.
Keywords: acylazole mediated; synthesis; stereoselective regioselective; mediated stereoselective ... See more keywords