Experiment Meets Theory: Cope Rearrangements and Thermal E/Z Isomerisations of Terpenoid Hydrocarbons
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202400583
Abstract: Several terpenes are known that can undergo a Cope rearrangement. Prominent examples include germacrene A and hedycaryol that show a Cope rearrangement already slightly above room temperature. In the present study the Cope rearrangements of… read more here.
Keywords: experiment meets; thermal isomerisations; theory cope; meets theory ... See more keywords
Confined molecules: experiment meets theory in small spaces
Sign Up to like & getrecommendations! Published in 2020 at "Quarterly Reviews of Biophysics"
DOI: 10.1017/s0033583520000049
Abstract: Abstract The behavior of molecules confined to small spaces is fascinating chemistry and lies at the heart of signaling processes in biology. Our approach to confinement is through reversible encapsulation of small molecules in synthetic… read more here.
Keywords: experiment meets; small spaces; molecules experiment; meets theory ... See more keywords