Highly Selective Aluminum(III) Ion Sensing with Luminescent Iridium(III) Complexes Bearing a Distorted 2,2'-Bipyridine-3,3'-diol Moiety Utilizing a Rigidified Seven-Membered Chelate Ring.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00373
Abstract: To create an ion sensor utilizing a rigidified seven-membered chelate ring, we developed two Ir(III) complexes with 2,2'-bipyridine-3,3'-diol (bpy(OH)2, bpydL) ligands as reaction centers, namely Ir1 ([Ir(ppy)2{bpy(O-)(OH)}], ppy = 2-phenylpyridine) and Ir2 ([Ir(bzq)2{bpy(O-)(OH)}], bzq =… read more here.
Keywords: iii; chelate ring; membered chelate; seven membered ... See more keywords
Influence of Substituents in a Six-Membered Chelate Ring of HG-Type Complexes Containing an N→Ru Bond on Their Stability and Catalytic Activity
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031188
Abstract: An efficient approach to the synthesis of olefin metathesis HG-type catalysts containing an N→Ru bond in a six-membered chelate ring was proposed. For the most part, these ruthenium chelates can be prepared easily and in… read more here.
Keywords: catalytic activity; containing bond; chelate; chelate ring ... See more keywords