The Origins of Dramatic Differences in Five-Membered vs Six-Membered Chelation of Pd(II) on Efficiency of C(sp3)-H Bond Activation.
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DOI: 10.1021/jacs.7b01801
Abstract: The origin of the unique effectiveness of six-membered chelates on the β-methylene C(sp3)-H activation reactions by Pd(II) catalyst was explained with density functional theory. The Pd(II) catalysts that involve five-membered chelates are inactive in this… read more here.
Keywords: six membered; membered chelation; bond activation; five membered ... See more keywords