Ruthenium-Catalyzed Sequential Hydrosilylation/Dehydrogenation and C-H Silylation: Synthesis of Six-Membered Indole Silacycles and Pyrrole Silyl Ether Cycles.
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DOI: 10.1021/acs.orglett.4c01949
Abstract: Selective dehydrogenative C-H silylation is one of the most powerful tools to synthesize silacycles. Herein, we developed Ru-catalyzed sequential hydrosilylation/C-H silylation of allyl-indoles and dehydrogenative O-H/C-H silylation of pyrrole phenols. Both six-membered indole silacycles and… read more here.
Keywords: catalyzed sequential; sequential hydrosilylation; membered indole; six membered ... See more keywords