Controlled Access to Four- and Six-Membered Palladacycles via Modifying Donor Abilities of β-Ketiminato Ligands ("NacAcs").
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DOI: 10.1021/acs.inorgchem.2c03515
Abstract: The synthesis of Pd complexes of the type [PdBr(iPr2-bimy)(NacAc)] (NacAc = β-ketiminate, iPr2-bimy = 1,3-diisopropylbenzimidazolin-2-ylidene) was attempted, in a continuing effort to quantify donor abilities of chelating β-ketiminate ligands using the Huynh electronic parameter for… read more here.
Keywords: donor abilities; membered palladacycles; controlled access; six membered ... See more keywords