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Published in 2020 at "Current opinion in structural biology"
DOI: 10.1016/j.sbi.2020.05.005
Abstract: Menaquinones (vitamin K2) are a family of redox-active small molecules with critical functions across all domains of life, including energy generation in bacteria and bone health in humans. The enzymes involved in menaquinone biosynthesis also…
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Keywords:
biosynthesis;
advances menaquinone;
biosynthesis sublocalisation;
menaquinone biosynthesis ... See more keywords
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Published in 2021 at "Biochemistry"
DOI: 10.1021/acs.biochem.1c00181
Abstract: Aminofutalosine synthase (MqnE) is a radical SAM enzyme that catalyzes the conversion of 3-((1-carboxyvinyl)oxy)benzoic acid to aminofutalosine during the futalosine-dependent menaquinone biosynthesis. In this Communication, we report the trapping of a radical intermediate in the…
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Keywords:
catalyzed reaction;
menaquinone biosynthesis;
biosynthesis new;
mqne catalyzed ... See more keywords