New functionalized ditopic redox-active hydroxy-p-iminoquinone-type ligands and mercury(ii) complexes based on these ligands
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DOI: 10.1007/s11172-020-2722-x
Abstract: New bis-p-iminobenzoquinone ligands, in which two hydroxy-p-iminobenzoquinone moieties are bridged by various functionalized linkers, were synthesized by 1,4-addition of aromatic diamines to 3,6-di-tert-butyl-o-benzoquinone. The exchange reaction between potassium salts of new ligands and ethylmercury(ii) chloride… read more here.
Keywords: ligands mercury; mercury complexes; functionalized ditopic; hydroxy ... See more keywords
Mercury(II) Complexes of Anionic N-Heterocyclic Carbene Ligands: Steric Effects of the Backbone Substituent
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DOI: 10.3390/molecules25163741
Abstract: Mercury(II) complexes (Me-maloNHCDipp)HgCl (1b), (t-Bu-maloNHCDipp)HgCl (2b) and (t-Bu-maloNHCDipp)HgMe (2c) supported by anionic N-heterocyclic carbenes have been obtained in good yields from the reaction of the potassium salt of N-heterocyclic carbene ligand precursors and mercury(II) salts,… read more here.
Keywords: mercury complexes; anionic heterocyclic; backbone substituent; malonhcdipp hgcl ... See more keywords