Mercury halide coordination polymers exhibiting reversible structural transformation
Sign Up to like & getrecommendations! Published in 2018 at "CrystEngComm"
DOI: 10.1039/c8ce00086g
Abstract: Solvothermal reactions of HgX2 salts with the new bis-pyridyl-bis-amide ligand 2,2′-(1,3-phenylene)-bis(N-(pyridin-3-yl)acetamide) (1,3-pbpa) in acetonitrile afforded the complexes [Hg(1,3-pbpa)X2]n (X = Cl, 1; Br, 2; I, 3), while the complexes [Hg(1,3-pbpa)X2·MeCN]n (X = Br, 4; I,… read more here.
Keywords: structural transformation; reversible structural; transformation; coordination polymers ... See more keywords
Syntheses, Crystal Structures and Characterization of Two New Lanthanide Mercury Halide Compounds.
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DOI: 10.17344/acsi.2024.8937
Abstract: Two new lanthanide mercury halide compounds with isonicotinic acid as a ligand, namely, [Gd(HIA)2(IA)(H2O)2(HgCl2)]n(nHgCl4)·3nH2O (1) (HIA = isonicotinic acid) and {[Nd(HIA)3(DMF)(H2O)]n}[(Hg4Br11)n](2HgBr2)(nBr)·nH3O·0.5nH2O (2) (DMF = N,N'-Dimethylformamide), were synthesized by means of solvothermal reactions and characterized by… read more here.
Keywords: lanthanide mercury; mercury; two new; mercury halide ... See more keywords