Solventless, selective and catalytic oxidation of primary, secondary and benzylic alcohols by a Merrifield resin supported molybdenum(VI) complex with H2O2 as an oxidant
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DOI: 10.1039/c8ra05969a
Abstract: Here, we have described the synthesis, characterization and catalytic activity of a dioxo-molybdenum(VI) complex supported on functionalized Merrifield resin (MR-SB-Mo). The functionalization of Merrifield resin (MR) was achieved in two-steps viz. carbonylation (MR-C) and Schiff… read more here.
Keywords: molybdenum complex; h2o2 oxidant; merrifield resin;
Organic Salts and Merrifield Resin Supported [PM12O40]3− (M = Mo or W) as Catalysts for Adipic Acid Synthesis
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DOI: 10.3390/molecules24040783
Abstract: Adipic acid (AA) was obtained by catalyzed oxidation of cyclohexene, epoxycyclohexane, or cyclohexanediol under organic solvent-free conditions using aqueous hydrogen peroxide (30%) as an oxidizing agent and molybdenum- or tungsten-based Keggin polyoxometalates (POMs) surrounded by… read more here.
Keywords: supported pm12o40; resin supported; salts merrifield; adipic acid ... See more keywords