Synthesis of cobalt bis(8-methylthio-1,2-dicarbollide)- pentacarbonyltungsten complexes
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DOI: 10.1007/s11172-018-2112-9
Abstract: A reaction of Bu4N[8,8´-(MeS)2-3,3´-Co(1,2-C2B9H10)2] with (MeCN)3W(CO)3 in dichloromethane gave a mixture of Bu4N{(CO)5W[κ-8,8´-(MeS)2-3,3´-Co(1,2-C2B9H10)2]} and Bu4N{[(CO)5W]2[κ2-8,8´-(MeS)2-3,3´-Co(1,2-C2B9H10)2]}, which were separated by column chromatography on silica gel. read more here.
Keywords: cobalt bis; bu4n mes; methylthio dicarbollide; bis methylthio ... See more keywords