Articles with "mes dipp" as a keyword



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Titanium complexes with unsymmetrically substituted imidazolin-2-iminato ligands.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt01740g

Abstract: The reaction of the unsymmetrical N-heterocyclic carbenes 1-(2,4,6-trimethylphenyl)-3-(adamantyl)imidazolin-2-ylidene (IAdMes, 1a) and 1-(2,6-diisopropylphenyl)-3-(adamantyl)imidazolin-2-ylidene (IAdDipp, 1b) with trimethylsilyl azide furnished the 2-(trimethylsilylimino)imidazolines 2a (ImAdMesNSiMe3) and 2b (ImAdDippNSiMe3). Desilylation by stirring in methanol gave the corresponding imidazolin-2-imines 3a… read more here.

Keywords: titanium complexes; complexes unsymmetrically; imidazolin iminato; mes dipp ... See more keywords